Covalency between the uranyl ion and dithiophosphinate by sulfur K-edge X-ray absorption spectroscopy and density functional theory

Covalency between the uranyl ion and dithiophosphinate by sulfur K-edge X-ray absorption spectroscopy and density functional theory

The dithiophosphinic acids (HS2PR2) have been used for the selective separation of trivalent actinides (AnIII) from lanthanides (LnIII) over the past decades. The substituents on the dithiophosphinic acids dramatically impact the separation performance, but the mechanism is still open for debate. In...

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Bibliographic Details
Main Authors: Yusheng Zhang, Wuhua Duan, Qiang Wang, Lei Zheng, Jianchen Wang, Jing Chen, Taoxiang Sun
Format: Article
Language:English
Published: International Union of Crystallography 2022-01-01
Series:Journal of Synchrotron Radiation
Subjects:
covalency
uranyl ion
dithiophosphinate
x-ray absorption spectroscopy
density functional theory
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160057752101198X

Internet

http://scripts.iucr.org/cgi-bin/paper?S160057752101198X

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