Formal Anti‐Markovnikov Addition of Water to Olefins by Titanocene‐Catalyzed Epoxide Hydrosilylation: From Stoichiometric to Sustainable Catalytic Reactions

Abstract Here, the evolution of the titanocene‐catalyzed hydrosilylation of epoxides that yields the corresponding anti‐Markovnikov alcohols is summarized. The study focuses on aspects of sustainability, efficient catalyst activation, and stereoselectivity. The latest variant of the reaction employs...

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Bibliographic Details
Main Authors: Sebastian Höthker, Andreas Gansäuer
Format: Article
Language:English
Published: Wiley 2023-07-01
Series:Global Challenges
Subjects:
Online Access:https://doi.org/10.1002/gch2.202200240