Visible-Light Radical–Radical Coupling vs. Radical Addition: Disentangling a Mechanistic Knot

Visible-Light Radical–Radical Coupling vs. Radical Addition: Disentangling a Mechanistic Knot

A highly enantioselective protocol has been recently described as allowing the synthesis of five-membered cyclic imines harnessing the selective generation of a β-Csp<sup>3</sup>-centered radical of acyl heterocyclic derivatives and its subsequent interaction with diverse NH-ketimines. T...

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Bibliographic Details
Main Authors: Fernando Aguilar-Galindo, Ricardo I. Rodríguez, Leonardo Mollari, José Alemán, Sergio Díaz-Tendero
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Catalysts
Subjects:
photocatalysis
density functional theory
pyrroline derivative
radical addition
radical–radical coupling
asymmetric synthesis
Online Access:https://www.mdpi.com/2073-4344/11/8/922

Internet

https://www.mdpi.com/2073-4344/11/8/922

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