Enzymatic preparation of mono- and diacylglycerols: A review
Monoacylglycerols (MAGs) and diacylglycerols (DAGs) are partial glycerides widely used in food industry. They are safe and non-toxic food emulsifiers, especially for MAGs. MAGs account for approximately 75% of the total emulsifiers in food industry worldwide. DAGs are recognized as functional cookin...
Main Authors: | , , , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
KeAi Communications Co., Ltd.
2023-12-01
|
Series: | Grain & Oil Science and Technology |
Subjects: | |
Online Access: | http://www.sciencedirect.com/science/article/pii/S2590259823000316 |
_version_ | 1797383644993552384 |
---|---|
author | Jiawei Zheng Yudong Liang Jiaxi Li Shuping Lin Qiangyue Zhang Kanghua Zuo Nanjing Zhong Xuebing Xu |
author_facet | Jiawei Zheng Yudong Liang Jiaxi Li Shuping Lin Qiangyue Zhang Kanghua Zuo Nanjing Zhong Xuebing Xu |
author_sort | Jiawei Zheng |
collection | DOAJ |
description | Monoacylglycerols (MAGs) and diacylglycerols (DAGs) are partial glycerides widely used in food industry. They are safe and non-toxic food emulsifiers, especially for MAGs. MAGs account for approximately 75% of the total emulsifiers in food industry worldwide. DAGs are recognized as functional cooking oils, they can suppress body fat accumulation and postprandial serum triacylglycerols (TAGs) level. The traditional production of MAGs and DAGs is based on the chemical method, which requires high reaction temperature usually up to 200–260 °C. Such high temperature is not suitable for oil containing heat sensitive polyunsaturated fatty acids. Enzymatic approach has been received increasing attentions. Enzymatic production of partial glycerides to replace chemical processes has been in industry, particularly for DAGs production as the products have been claimed as a functional and nutritional oil. Enzyme technology for the processing of oils and fats has been moved to industry step by step and case by case during the last 20 years. More and more applications are particularly moving into bulky oils and fats processing. At the same time, the cost of enzymes as a commercial product is reducing steadily. This review summarized the recent 15 years advances on the the enzymatic preparation of MAGs and DAGs. The critical process parameters under different reaction routes were presented and emphasized. The reaction media not only increased the homogeneity of the reaction system, but also shifted the reaction equilibrium towards the target product generation, and this part was stated in detail. In addition, the patent evaluation was included, and the application of MAGs and DAGs was covered. |
first_indexed | 2024-03-08T21:24:03Z |
format | Article |
id | doaj.art-34161ae96ca04de281963e233cdad65e |
institution | Directory Open Access Journal |
issn | 2590-2598 |
language | English |
last_indexed | 2024-03-08T21:24:03Z |
publishDate | 2023-12-01 |
publisher | KeAi Communications Co., Ltd. |
record_format | Article |
series | Grain & Oil Science and Technology |
spelling | doaj.art-34161ae96ca04de281963e233cdad65e2023-12-21T07:37:17ZengKeAi Communications Co., Ltd.Grain & Oil Science and Technology2590-25982023-12-0164185205Enzymatic preparation of mono- and diacylglycerols: A reviewJiawei Zheng0Yudong Liang1Jiaxi Li2Shuping Lin3Qiangyue Zhang4Kanghua Zuo5Nanjing Zhong6Xuebing Xu7School of Food Science, Guangdong Pharmaceutical University, Zhongshan 528458, ChinaCollege of Food Science and Technology, Henan University of Technology, Zhengzhou 450001, ChinaCollege of Food Science and Technology, Henan University of Technology, Zhengzhou 450001, ChinaSchool of Food Science, Guangdong Pharmaceutical University, Zhongshan 528458, ChinaSchool of Food Science, Guangdong Pharmaceutical University, Zhongshan 528458, ChinaWilmar (Shanghai) Biotechnology Research and Development Center Ltd., Pudong New District, Shanghai 200137, ChinaSchool of Food Science, Guangdong Pharmaceutical University, Zhongshan 528458, China; Corresponding authors.Wilmar (Shanghai) Biotechnology Research and Development Center Ltd., Pudong New District, Shanghai 200137, China; Corresponding authors.Monoacylglycerols (MAGs) and diacylglycerols (DAGs) are partial glycerides widely used in food industry. They are safe and non-toxic food emulsifiers, especially for MAGs. MAGs account for approximately 75% of the total emulsifiers in food industry worldwide. DAGs are recognized as functional cooking oils, they can suppress body fat accumulation and postprandial serum triacylglycerols (TAGs) level. The traditional production of MAGs and DAGs is based on the chemical method, which requires high reaction temperature usually up to 200–260 °C. Such high temperature is not suitable for oil containing heat sensitive polyunsaturated fatty acids. Enzymatic approach has been received increasing attentions. Enzymatic production of partial glycerides to replace chemical processes has been in industry, particularly for DAGs production as the products have been claimed as a functional and nutritional oil. Enzyme technology for the processing of oils and fats has been moved to industry step by step and case by case during the last 20 years. More and more applications are particularly moving into bulky oils and fats processing. At the same time, the cost of enzymes as a commercial product is reducing steadily. This review summarized the recent 15 years advances on the the enzymatic preparation of MAGs and DAGs. The critical process parameters under different reaction routes were presented and emphasized. The reaction media not only increased the homogeneity of the reaction system, but also shifted the reaction equilibrium towards the target product generation, and this part was stated in detail. In addition, the patent evaluation was included, and the application of MAGs and DAGs was covered.http://www.sciencedirect.com/science/article/pii/S2590259823000316MonoacylglycerolDiacylglycerolEnzymatic productionEsterificationGlycerolysisTert-butanol |
spellingShingle | Jiawei Zheng Yudong Liang Jiaxi Li Shuping Lin Qiangyue Zhang Kanghua Zuo Nanjing Zhong Xuebing Xu Enzymatic preparation of mono- and diacylglycerols: A review Grain & Oil Science and Technology Monoacylglycerol Diacylglycerol Enzymatic production Esterification Glycerolysis Tert-butanol |
title | Enzymatic preparation of mono- and diacylglycerols: A review |
title_full | Enzymatic preparation of mono- and diacylglycerols: A review |
title_fullStr | Enzymatic preparation of mono- and diacylglycerols: A review |
title_full_unstemmed | Enzymatic preparation of mono- and diacylglycerols: A review |
title_short | Enzymatic preparation of mono- and diacylglycerols: A review |
title_sort | enzymatic preparation of mono and diacylglycerols a review |
topic | Monoacylglycerol Diacylglycerol Enzymatic production Esterification Glycerolysis Tert-butanol |
url | http://www.sciencedirect.com/science/article/pii/S2590259823000316 |
work_keys_str_mv | AT jiaweizheng enzymaticpreparationofmonoanddiacylglycerolsareview AT yudongliang enzymaticpreparationofmonoanddiacylglycerolsareview AT jiaxili enzymaticpreparationofmonoanddiacylglycerolsareview AT shupinglin enzymaticpreparationofmonoanddiacylglycerolsareview AT qiangyuezhang enzymaticpreparationofmonoanddiacylglycerolsareview AT kanghuazuo enzymaticpreparationofmonoanddiacylglycerolsareview AT nanjingzhong enzymaticpreparationofmonoanddiacylglycerolsareview AT xuebingxu enzymaticpreparationofmonoanddiacylglycerolsareview |