Reduction of Triple Bond in [B<sub>12</sub>H<sub>11</sub>NCR]<sup>−</sup> Anions by Lithium Aluminum Hydride: A Novel Approach to the Synthesis of N-Monoalkylammonio-Substituted <i>closo</i>-Dodecaborates

Reduction of Triple Bond in [B<sub>12</sub>H<sub>11</sub>NCR]<sup>−</sup> Anions by Lithium Aluminum Hydride: A Novel Approach to the Synthesis of N-Monoalkylammonio-Substituted <i>closo</i>-Dodecaborates

By reacting nitrilium derivative of the <i>closo</i>-dodecaborate anion, Bu<sub>4</sub>N[B<sub>12</sub>H<sub>11</sub>N≡CR] (where R = Me, Et, nPr, iPr, p-tolyl), with lithium aluminum hydride (LiAlH<sub>4</sub>), N-alkylammonium derivatives...

Full description

Bibliographic Details
Main Authors: Alexey V. Nelyubin, Nikolay K. Neumolotov, Nikita A. Selivanov, Alexander Yu. Bykov, Ilya N. Klyukin, Alexander S. Novikov, Alexey S. Kubasov, Andrey P. Zhdanov, Konstantin Yu. Zhizhin, Nikolay T. Kuznetsov
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Inorganics
Subjects:
nitrilium derivative
<i>closo</i>-dodecaborate anion
reduction
Online Access:https://www.mdpi.com/2304-6740/12/1/2

Internet

https://www.mdpi.com/2304-6740/12/1/2

Similar Items