Hypervalent Iodine(III)-Induced Domino Oxidative Cyclization for the Synthesis of Cyclopenta[b]furans

Hypervalent Iodine(III)-Induced Domino Oxidative Cyclization for the Synthesis of Cyclopenta[b]furans

A new strategy for cyclopenta[b]furan synthesis mediated by hypervalent iodine(III) has been described. The approach employs diacetoxyiodobenzene-induced initial dehydrogenation to a putative trienone intermediate and triggered sequential cycloisomerization to form the cyclo-penta[b]furan targets.

Bibliographic Details
Main Authors: Mei-Huey Lin, Yu-Chun Chen, Shih-Hao Chiu, Yun-Fan Chen, Tsung-Hsun Chuang
Format: Article
Language:English
Published: MDPI AG 2016-12-01
Series:Molecules
Subjects:
cyclopenta[b]furan
hypervalent iodine(III)
domino oxidative cyclization
diacetoxyiodobenzene
cycloisomerization
Online Access:http://www.mdpi.com/1420-3049/21/12/1713

Internet

http://www.mdpi.com/1420-3049/21/12/1713

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