Organoleptic Chemical Markers of Serpa PDO Cheese Specificity

Serpa is a protected designation of origin cheese produced with a vegetable coagulant (<i>Cynara cardunculus</i> L.) and raw ovine milk. Despite the unique sensory profile of raw milk cheeses, numerous parameters influence their sensory properties and safety. To protect the Serpa cheese...

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Main Authors: Helena Araújo-Rodrigues, António P. L. Martins, Freni K. Tavaria, Maria Teresa G. Santos, Maria João Carvalho, João Dias, Nuno B. Alvarenga, Manuela E. Pintado
Format: Article
Language:English
Published: MDPI AG 2022-06-01
Series:Foods
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Online Access:https://www.mdpi.com/2304-8158/11/13/1898
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author Helena Araújo-Rodrigues
António P. L. Martins
Freni K. Tavaria
Maria Teresa G. Santos
Maria João Carvalho
João Dias
Nuno B. Alvarenga
Manuela E. Pintado
author_facet Helena Araújo-Rodrigues
António P. L. Martins
Freni K. Tavaria
Maria Teresa G. Santos
Maria João Carvalho
João Dias
Nuno B. Alvarenga
Manuela E. Pintado
author_sort Helena Araújo-Rodrigues
collection DOAJ
description Serpa is a protected designation of origin cheese produced with a vegetable coagulant (<i>Cynara cardunculus</i> L.) and raw ovine milk. Despite the unique sensory profile of raw milk cheeses, numerous parameters influence their sensory properties and safety. To protect the Serpa cheese quality and contribute to unifying their distinctive features, some rheologic and physicochemical parameters of cheeses from four PDO producers, in distinct seasons and with different sensory scores, were monitored. The results suggested a high chemical diversity and variation according to the dairy, month and season, which corroborates the significant heterogeneity. However, a higher incidence of some compounds was found: a group of free amino acids (Glu, Ala, Leu, Val and Phe), lactic and acetic acids, some volatile fatty acids (e.g., iC4, iC5, C6 and C12) and esters (e.g., ethyl butanoate, decanoate and dodecanoate). Through the successive statistical analysis, 13 variables were selected as chemical markers of Serpa cheese specificity: C<sub>3</sub>, C<sub>4</sub>, iC<sub>5</sub>, C<sub>12</sub>, Tyr, Trp, Ile, 2-undecanone, ethyl isovalerate, moisture content on a fat-free basis, the nitrogen-fractions (maturation index and non-protein and total nitrogen ratio) and G’ <sub>1 Hz</sub>. These sensory markers’ identification will be essential to guide the selection and development of an autochthonous starter culture to improve cheese quality and safety issues and maintain some of the Serpa authenticity.
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spelling doaj.art-34b6c9913dad417c87e7796b12f094892023-11-23T20:01:03ZengMDPI AGFoods2304-81582022-06-011113189810.3390/foods11131898Organoleptic Chemical Markers of Serpa PDO Cheese SpecificityHelena Araújo-Rodrigues0António P. L. Martins1Freni K. Tavaria2Maria Teresa G. Santos3Maria João Carvalho4João Dias5Nuno B. Alvarenga6Manuela E. Pintado7CBQF—Centro de Biotecnologia e Química Fina, Laboratório Associado, Escola Superior de Biotecnologia, Universidade Católica Portuguesa, Rua Diogo Botelho 1327, 4169-005 Porto, PortugalInstituto Nacional de Investigação Agrária e Veterinária, Unidade de Tecnologia e Inovação, Avenida da República, Quinta do Marquês, 2780-157 Oeiras, PortugalCBQF—Centro de Biotecnologia e Química Fina, Laboratório Associado, Escola Superior de Biotecnologia, Universidade Católica Portuguesa, Rua Diogo Botelho 1327, 4169-005 Porto, PortugalEscola Superior Agrária, Instituto Politécnico de Beja, Rua Pedro Soares, 7800-295 Beja, PortugalEscola Superior Agrária, Instituto Politécnico de Beja, Rua Pedro Soares, 7800-295 Beja, PortugalGeobiosciences, Geobiotechnologies and Geoengineering (GeoBioTec), Faculdade de Ciências e Tecnologias, Universidade Nova de Lisboa, 2829-516 Caparica, PortugalInstituto Nacional de Investigação Agrária e Veterinária, Unidade de Tecnologia e Inovação, Avenida da República, Quinta do Marquês, 2780-157 Oeiras, PortugalCBQF—Centro de Biotecnologia e Química Fina, Laboratório Associado, Escola Superior de Biotecnologia, Universidade Católica Portuguesa, Rua Diogo Botelho 1327, 4169-005 Porto, PortugalSerpa is a protected designation of origin cheese produced with a vegetable coagulant (<i>Cynara cardunculus</i> L.) and raw ovine milk. Despite the unique sensory profile of raw milk cheeses, numerous parameters influence their sensory properties and safety. To protect the Serpa cheese quality and contribute to unifying their distinctive features, some rheologic and physicochemical parameters of cheeses from four PDO producers, in distinct seasons and with different sensory scores, were monitored. The results suggested a high chemical diversity and variation according to the dairy, month and season, which corroborates the significant heterogeneity. However, a higher incidence of some compounds was found: a group of free amino acids (Glu, Ala, Leu, Val and Phe), lactic and acetic acids, some volatile fatty acids (e.g., iC4, iC5, C6 and C12) and esters (e.g., ethyl butanoate, decanoate and dodecanoate). Through the successive statistical analysis, 13 variables were selected as chemical markers of Serpa cheese specificity: C<sub>3</sub>, C<sub>4</sub>, iC<sub>5</sub>, C<sub>12</sub>, Tyr, Trp, Ile, 2-undecanone, ethyl isovalerate, moisture content on a fat-free basis, the nitrogen-fractions (maturation index and non-protein and total nitrogen ratio) and G’ <sub>1 Hz</sub>. These sensory markers’ identification will be essential to guide the selection and development of an autochthonous starter culture to improve cheese quality and safety issues and maintain some of the Serpa authenticity.https://www.mdpi.com/2304-8158/11/13/1898Serpa PDO cheesechemical markerssensory analysisfree amino acidsorganic acidsvolatiles
spellingShingle Helena Araújo-Rodrigues
António P. L. Martins
Freni K. Tavaria
Maria Teresa G. Santos
Maria João Carvalho
João Dias
Nuno B. Alvarenga
Manuela E. Pintado
Organoleptic Chemical Markers of Serpa PDO Cheese Specificity
Foods
Serpa PDO cheese
chemical markers
sensory analysis
free amino acids
organic acids
volatiles
title Organoleptic Chemical Markers of Serpa PDO Cheese Specificity
title_full Organoleptic Chemical Markers of Serpa PDO Cheese Specificity
title_fullStr Organoleptic Chemical Markers of Serpa PDO Cheese Specificity
title_full_unstemmed Organoleptic Chemical Markers of Serpa PDO Cheese Specificity
title_short Organoleptic Chemical Markers of Serpa PDO Cheese Specificity
title_sort organoleptic chemical markers of serpa pdo cheese specificity
topic Serpa PDO cheese
chemical markers
sensory analysis
free amino acids
organic acids
volatiles
url https://www.mdpi.com/2304-8158/11/13/1898
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