Synthesis of α,β-unsaturated ketones through nickel-catalysed aldehyde-free hydroacylation of alkynes

Synthesis of α,β-unsaturated ketones through nickel-catalysed aldehyde-free hydroacylation of alkynes

Transition metal-catalysed hydroacylation of alkynes using aldehydes is an atom-economical route to access α,β-unsaturated ketones, but typically requires aldehydes that bear chelating moieties. Here, the authors report a nickel-catalysed anti-Markovnikov selective coupling process to afford non-tet...

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Những tác giả chính: Joon Ho Rhlee, Saikat Maiti, Jeong Woo Lee, Ho Seung Lee, Ismoili Ahror Bakhtiyorzoda, Soochan Lee, Jaehyun Park, Seok Ju Kang, Yung Sam Kim, Jeong Kon Seo, Kyungjae Myung, Wonyoung Choe, Sung You Hong
Định dạng: Bài viết
Ngôn ngữ:English
Được phát hành: Nature Portfolio 2022-02-01
Loạt:Communications Chemistry
Truy cập trực tuyến:https://doi.org/10.1038/s42004-022-00633-3

Internet

https://doi.org/10.1038/s42004-022-00633-3

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