Poly[pentakis(μ-cyanido-κ2N:C)tris(5-phenyl-2,2′-bipyridine-κ2N,N′)pentacopper(I)]

The hydrothermal reaction of Cu(acetate)2 and K3[Fe(CN)6] with 5-phenyl-2,2′-bipyridine (5-ph-2,2′-bpy) in water yields the polymeric title complex, [Cu5(CN)5(C16H12N2)3]n, which consists of ribbons along the a axis, constructed from 26-membered {Cu10(CN)8} rings. In thes...

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Bibliographic Details
Main Authors: Shuxin Cui, Minghui Zuo, Jingping Zhang, Yulong Zhao, Rongxin Tan, Shujuan Liu, Shuangyue Su
Format: Article
Language:English
Published: International Union of Crystallography 2011-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811045910