Ring walking as a regioselectivity control element in Pd-catalyzed C-N cross-coupling
The phenomenon of „ring-walking‟, wherein a metal catalyst remains bound to a pi system as it migrates to another coupling site, is supported largely by circumstantial evidence. Here the authors perform an in-depth kinetic study of Buchwald- Hartwig animations with several catalytic systems delineat...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2022-05-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-022-30255-1 |