Synthesis of a Half-Sandwich Hydroxidoiridium(III) Complex Bearing a Nonprotic <i>N</i>-Sulfonyldiamine Ligand and Its Transformations Triggered by the Brønsted Basicity

Synthesis and reactivities of a new mononuclear hydroxidoiridium(III) complex with a pentamethylcyclopentadienyl (Cp*) ligand are reported. The hydroxido ligand was introduced into an iridium complex having a nonprotic amine chelate derived from <i>N</i>-mesyl-<i>N</i>&#8...

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Bibliographic Details
Main Authors: Shoko Kamezaki, Yoshihito Kayaki, Shigeki Kuwata, Takao Ikariya
Format: Article
Language:English
Published: MDPI AG 2019-10-01
Series:Inorganics
Subjects:
Online Access:https://www.mdpi.com/2304-6740/7/10/125