Nanoporous Frameworks with High Porosity and Unexpected Rigid Framework Topologies Based on Odd‐Numbered Ring‐Expanded Linkers

Nanoporous Frameworks with High Porosity and Unexpected Rigid Framework Topologies Based on Odd‐Numbered Ring‐Expanded Linkers

Two tetracarboxylic linkers containing seven‐membered rings are synthesized and utilized in metal–organic framework (MOF) syntheses, leading to the two new compounds DUT‐184 and DUT‐193. The introduced odd angles between carboxylates in a new dihydro‐azepine‐containing linker lead to exotic Zn‐based...

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Bibliographic Details
Main Authors: Bodo Felsner, Karuppasamy Gopalsamy, Volodymyr Bon, Irena Senkovska, Guillaume Maurin, Stefan Kaskel
Format: Article
Language:English
Published: Wiley-VCH 2023-12-01
Series:Small Science
Subjects:
bff
catenations
dihydro azepine rings
high porosities
metal–organic frameworks (MOFs)
new topologies
Online Access:https://doi.org/10.1002/smsc.202300158

Internet

https://doi.org/10.1002/smsc.202300158

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