Tetrakis(acetonitrile-κN)lithium hexafluoridophosphate acetonitrile monosolvate
In the title compound, [Li(CH3CN)4]PF6·CH3CN, the asymmetric unit consists of three independent tetrahedral [Li(CH3CN)4]+ cations, three uncoordinated PF6− anions and three uncoordinated CH3CN solvent molecules. The three anions are disordered over two sites through a rota...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811027528 |
| Summary: | In the title compound, [Li(CH3CN)4]PF6·CH3CN, the asymmetric unit consists of three independent tetrahedral [Li(CH3CN)4]+ cations, three uncoordinated PF6− anions and three uncoordinated CH3CN solvent molecules. The three anions are disordered over two sites through a rotation along one of the F—P—F axes. The relative occupancies of the two sites for the F atoms are 0.643 (16):0.357 (16), 0.677 (10):0.323 (10) and 0.723 (13):0.277 (13). The crystal used was a racemic twin, with approximately equal twin components. |
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| ISSN: | 1600-5368 |