STUDIES ON THE WATER SOLUBILIZATION PROCESSES OF OENOTANNINS AND THEIR PHYSICO-CHEMICAL PROPERTIES

The results of investigation of oenotannins content in the seeds of different grape varieties are presented in the paper. It was demonstrated that the oenotannins content depends on the grape variety as well as on the geographycal zone of grape cultivation. A new procedure for water sollubilization...

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Main Authors: Gh. Duca, T. Lupaşcu, P. Vlad, V. Kulciţki, R. Nastas
Format: Article
Language:English
Published: Academy of Sciences of Moldova, Institute of Chemistry 2006-06-01
Series:Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
Subjects:
Online Access:http://www.cjm.asm.md/sites/default/files/article_files/AA-0017_060.pdf
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author Gh. Duca
T. Lupaşcu
P. Vlad
V. Kulciţki
R. Nastas
author_facet Gh. Duca
T. Lupaşcu
P. Vlad
V. Kulciţki
R. Nastas
author_sort Gh. Duca
collection DOAJ
description The results of investigation of oenotannins content in the seeds of different grape varieties are presented in the paper. It was demonstrated that the oenotannins content depends on the grape variety as well as on the geographycal zone of grape cultivation. A new procedure for water sollubilization of oenotannins by depolimerization has been elaborated. The mechanism of the oenotannins depolimerization has been reveiled by mass-spectrometric studies. It has been established, that the depolimerization process brings about formation of carboxilic acids and organic peroxides. The presence of the carboxilic and peroxidic groups was detremined on the basis of IR spectral analysis. It was demonstrated that the antioxidant properties of modified tannins are higher then those of initial unmodified ones.
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spelling doaj.art-372353f4333b46a6882077a599fcd9b02022-12-21T22:06:58ZengAcademy of Sciences of Moldova, Institute of ChemistryChemistry Journal of Moldova: General, Industrial and Ecological Chemistry1857-17272345-16882006-06-01116064STUDIES ON THE WATER SOLUBILIZATION PROCESSES OF OENOTANNINS AND THEIR PHYSICO-CHEMICAL PROPERTIESGh. Duca0T. Lupaşcu1P. Vlad2V. Kulciţki3R. Nastas4 Academy of Sciences of Moldova, Republic of MoldovaInstitute of Chemistry, Academy of Sciences of Moldova, Republic of MoldovaInstitute of Chemistry, Academy of Sciences of Moldova, Republic of MoldovaInstitute of Chemistry, Academy of Sciences of Moldova, Republic of MoldovaInstitute of Chemistry, Academy of Sciences of Moldova, Republic of MoldovaThe results of investigation of oenotannins content in the seeds of different grape varieties are presented in the paper. It was demonstrated that the oenotannins content depends on the grape variety as well as on the geographycal zone of grape cultivation. A new procedure for water sollubilization of oenotannins by depolimerization has been elaborated. The mechanism of the oenotannins depolimerization has been reveiled by mass-spectrometric studies. It has been established, that the depolimerization process brings about formation of carboxilic acids and organic peroxides. The presence of the carboxilic and peroxidic groups was detremined on the basis of IR spectral analysis. It was demonstrated that the antioxidant properties of modified tannins are higher then those of initial unmodified ones.http://www.cjm.asm.md/sites/default/files/article_files/AA-0017_060.pdfphysico-chemical propertieswater solubilizationoenotannins
spellingShingle Gh. Duca
T. Lupaşcu
P. Vlad
V. Kulciţki
R. Nastas
STUDIES ON THE WATER SOLUBILIZATION PROCESSES OF OENOTANNINS AND THEIR PHYSICO-CHEMICAL PROPERTIES
Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry
physico-chemical properties
water solubilization
oenotannins
title STUDIES ON THE WATER SOLUBILIZATION PROCESSES OF OENOTANNINS AND THEIR PHYSICO-CHEMICAL PROPERTIES
title_full STUDIES ON THE WATER SOLUBILIZATION PROCESSES OF OENOTANNINS AND THEIR PHYSICO-CHEMICAL PROPERTIES
title_fullStr STUDIES ON THE WATER SOLUBILIZATION PROCESSES OF OENOTANNINS AND THEIR PHYSICO-CHEMICAL PROPERTIES
title_full_unstemmed STUDIES ON THE WATER SOLUBILIZATION PROCESSES OF OENOTANNINS AND THEIR PHYSICO-CHEMICAL PROPERTIES
title_short STUDIES ON THE WATER SOLUBILIZATION PROCESSES OF OENOTANNINS AND THEIR PHYSICO-CHEMICAL PROPERTIES
title_sort studies on the water solubilization processes of oenotannins and their physico chemical properties
topic physico-chemical properties
water solubilization
oenotannins
url http://www.cjm.asm.md/sites/default/files/article_files/AA-0017_060.pdf
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AT pvlad studiesonthewatersolubilizationprocessesofoenotanninsandtheirphysicochemicalproperties
AT vkulcitki studiesonthewatersolubilizationprocessesofoenotanninsandtheirphysicochemicalproperties
AT rnastas studiesonthewatersolubilizationprocessesofoenotanninsandtheirphysicochemicalproperties