The Origin of Stereoselectivity in the Hydrogenation of Oximes Catalyzed by Iridium Complexes: A DFT Mechanistic Study

The Origin of Stereoselectivity in the Hydrogenation of Oximes Catalyzed by Iridium Complexes: A DFT Mechanistic Study

Herein the reaction mechanism and the origin of stereoselectivity of asymmetric hydrogenation of oximes to hydroxylamines catalyzed by the cyclometalated iridium (III) complexes with chiral substituted single cyclopentadienyl ligands (Ir catalysts <b>A1</b> and <b>B1</b>) und...

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Bibliographic Details
Main Authors: Qaim Ali, Yongyong Chen, Ruixue Zhang, Zhewei Li, Yanhui Tang, Min Pu, Ming Lei
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Molecules
Subjects:
DFT
non-covalent interactions
stereoselectivity
asymmetric hydrogenation
oxime
Online Access:https://www.mdpi.com/1420-3049/27/23/8349

Internet

https://www.mdpi.com/1420-3049/27/23/8349

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