Towards an Asymmetric Organocatalytic α-Azidation of β-Ketoesters

Towards an Asymmetric Organocatalytic α-Azidation of β-Ketoesters

Detailed investigations concerning the organocatalytic (asymmetric) α-azidation of prochiral β-ketoesters were carried out. It was shown that the racemic version of such a reaction can either be carried out under oxidative conditions using TMSN3 as the azide-source with quaternary...

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Bibliographic Details
Main Authors: Maximilian Tiffner, Lotte Stockhammer, Johannes Schörgenhumer, Katharina Röser, Mario Waser
Format: Article
Language:English
Published: MDPI AG 2018-05-01
Series:Molecules
Subjects:
azides
organocatalysis
hypervalent iodine reagents
ammonium iodides
cinchona alkaloids
Online Access:http://www.mdpi.com/1420-3049/23/5/1142

Internet

http://www.mdpi.com/1420-3049/23/5/1142

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