The Asymmetry is Derived from Mechanical Interlocking of Achiral Axle and Achiral Ring Components –Syntheses and Properties of Optically Pure [2]Rotaxanes–

The Asymmetry is Derived from Mechanical Interlocking of Achiral Axle and Achiral Ring Components –Syntheses and Properties of Optically Pure [2]Rotaxanes–

Rotaxanes consisting of achiral axle and achiral ring components can possess supramolecular chirality due to their unique geometrical architectures. To synthesize such chiral rotaxanes, we adapted a prerotaxane method based on aminolysis of a metacyclophane type prerotaxane that had planar chirality...

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Bibliographic Details
Main Authors: Keiji Hirose, Masaya Ukimi, Shota Ueda, Chie Onoda, Ryohei Kano, Kyosuke Tsuda, Yuko Hinohara, Yoshito Tobe
Format: Article
Language:English
Published: MDPI AG 2018-01-01
Series:Symmetry
Subjects:
mechanical chirality
mecanostereochemistery
supramolecular chirality
rotaxane
aminolysis
Online Access:http://www.mdpi.com/2073-8994/10/1/20

Internet

http://www.mdpi.com/2073-8994/10/1/20

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