Crystal structure of μ3-tetrathioantimonato-tris[(cyclam)zinc(II)] tetrathioantimonate acetonitrile disolvate dihydrate showing Zn disorder over the cyclam ring planes (cyclam = 1,4,8,11-tetraazacyclotetradecane)

Crystal structure of μ3-tetrathioantimonato-tris[(cyclam)zinc(II)] tetrathioantimonate acetonitrile disolvate dihydrate showing Zn disorder over the cyclam ring planes (cyclam = 1,4,8,11-tetraazacyclotetradecane)

Reaction of Zn(ClO4)2·6H2O with cyclam (cyclam = 1,4,8,11-tetraazacyclotetradecane, C10H24N4) and Na3SbS4 in an acetonitrile/water mixture led to the formation of crystals of the title compound, [Zn3(SbS4)(C10H24N4)3](SbS4)·2CH3CN·2H2O or [(Zn-cyclam)3(SbS4)2](H2O)2(acetonitrile)2. The set-up of the...

Full description

Bibliographic Details
Main Authors: Christian Näther, Felix Danker, Wolfgang Bensch
Format: Article
Language:English
Published: International Union of Crystallography 2022-05-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
zn-thioantimonate
cation disorder
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989022003759

Internet

http://scripts.iucr.org/cgi-bin/paper?S2056989022003759

Similar Items