Methods of synthesis of metallaboranes with polyhedral cage [MB<sub>9</sub>H<sub>9</sub>], M=Ni, Pd
A new method of synthesis of polyhedral metallaboranes [ MB9 H9 ] ( M = Ni , Pd ) with an apical metal atom was suggested . The method consists in a reaction between ((C6H5)4P)2[B9H9] and different metal complexes of Ni(I), Ni(II) and Pd(II) both in organic solutions and in solid state with mechanic...
Main Authors: | , , , , , |
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Format: | Article |
Language: | Russian |
Published: |
MIREA - Russian Technological University
2012-12-01
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Series: | Тонкие химические технологии |
Subjects: | |
Online Access: | https://www.finechem-mirea.ru/jour/article/view/677 |