Methods of synthesis of metallaboranes with polyhedral cage [MB<sub>9</sub>H<sub>9</sub>], M=Ni, Pd
A new method of synthesis of polyhedral metallaboranes [ MB9 H9 ] ( M = Ni , Pd ) with an apical metal atom was suggested . The method consists in a reaction between ((C6H5)4P)2[B9H9] and different metal complexes of Ni(I), Ni(II) and Pd(II) both in organic solutions and in solid state with mechanic...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2012-12-01
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| Series: | Тонкие химические технологии |
| Subjects: | |
| Online Access: | https://www.finechem-mirea.ru/jour/article/view/677 |
| _version_ | 1797882096030580736 |
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| author | A. Yu. Bykov N. A. Selivanov N. A. Votinova N. B. Generalova K. Yu. Zhizhin N. T. Kuznetsov |
| author_facet | A. Yu. Bykov N. A. Selivanov N. A. Votinova N. B. Generalova K. Yu. Zhizhin N. T. Kuznetsov |
| author_sort | A. Yu. Bykov |
| collection | DOAJ |
| description | A new method of synthesis of polyhedral metallaboranes [ MB9 H9 ] ( M = Ni , Pd ) with an apical metal atom was suggested . The method consists in a reaction between ((C6H5)4P)2[B9H9] and different metal complexes of Ni(I), Ni(II) and Pd(II) both in organic solutions and in solid state with mechanical activation. The obtained metallaboranes were described with IR, NMR spectral data and elemental analysis. |
| first_indexed | 2024-04-10T03:30:37Z |
| format | Article |
| id | doaj.art-39327c5b832a409fb9dac90d62ea3be7 |
| institution | Directory Open Access Journal |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| last_indexed | 2024-04-10T03:30:37Z |
| publishDate | 2012-12-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj.art-39327c5b832a409fb9dac90d62ea3be72023-03-13T07:25:33ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752012-12-01766468671Methods of synthesis of metallaboranes with polyhedral cage [MB<sub>9</sub>H<sub>9</sub>], M=Ni, PdA. Yu. Bykov0N. A. Selivanov1N. A. Votinova2N. B. Generalova3K. Yu. Zhizhin4N. T. Kuznetsov5M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571Институт общей и неорганической химии им. Н.С. Курнакова РАНM.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571Институт общей и неорганической химии им. Н.С. Курнакова РАНM.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571A new method of synthesis of polyhedral metallaboranes [ MB9 H9 ] ( M = Ni , Pd ) with an apical metal atom was suggested . The method consists in a reaction between ((C6H5)4P)2[B9H9] and different metal complexes of Ni(I), Ni(II) and Pd(II) both in organic solutions and in solid state with mechanical activation. The obtained metallaboranes were described with IR, NMR spectral data and elemental analysis.https://www.finechem-mirea.ru/jour/article/view/677boron hydrides, metallaboranes, nickel, palladium, nickelaboranes, palladaboranes, closoborates. |
| spellingShingle | A. Yu. Bykov N. A. Selivanov N. A. Votinova N. B. Generalova K. Yu. Zhizhin N. T. Kuznetsov Methods of synthesis of metallaboranes with polyhedral cage [MB<sub>9</sub>H<sub>9</sub>], M=Ni, Pd Тонкие химические технологии boron hydrides, metallaboranes, nickel, palladium, nickelaboranes, palladaboranes, closoborates. |
| title | Methods of synthesis of metallaboranes with polyhedral cage [MB<sub>9</sub>H<sub>9</sub>], M=Ni, Pd |
| title_full | Methods of synthesis of metallaboranes with polyhedral cage [MB<sub>9</sub>H<sub>9</sub>], M=Ni, Pd |
| title_fullStr | Methods of synthesis of metallaboranes with polyhedral cage [MB<sub>9</sub>H<sub>9</sub>], M=Ni, Pd |
| title_full_unstemmed | Methods of synthesis of metallaboranes with polyhedral cage [MB<sub>9</sub>H<sub>9</sub>], M=Ni, Pd |
| title_short | Methods of synthesis of metallaboranes with polyhedral cage [MB<sub>9</sub>H<sub>9</sub>], M=Ni, Pd |
| title_sort | methods of synthesis of metallaboranes with polyhedral cage mb sub 9 sub h sub 9 sub m ni pd |
| topic | boron hydrides, metallaboranes, nickel, palladium, nickelaboranes, palladaboranes, closoborates. |
| url | https://www.finechem-mirea.ru/jour/article/view/677 |
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