Methods of synthesis of metallaboranes with polyhedral cage [MB<sub>9</sub>H<sub>9</sub>], M=Ni, Pd

Methods of synthesis of metallaboranes with polyhedral cage [MB<sub>9</sub>H<sub>9</sub>], M=Ni, Pd

A new method of synthesis of polyhedral metallaboranes [ MB9 H9 ] ( M = Ni , Pd ) with an apical metal atom was suggested . The method consists in a reaction between ((C6H5)4P)2[B9H9] and different metal complexes of Ni(I), Ni(II) and Pd(II) both in organic solutions and in solid state with mechanic...

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Bibliographic Details
Main Authors:	A. Yu. Bykov, N. A. Selivanov, N. A. Votinova, N. B. Generalova, K. Yu. Zhizhin, N. T. Kuznetsov
Format:	Article
Language:	Russian
Published:	MIREA - Russian Technological University 2012-12-01
Series:	Тонкие химические технологии
Subjects:	boron hydrides, metallaboranes, nickel, palladium, nickelaboranes, palladaboranes, closoborates.
Online Access:	https://www.finechem-mirea.ru/jour/article/view/677

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