Intraannular photoreactions in pseudo-geminally substituted [2.2]paracyclophanes

Intraannular photoreactions in pseudo-geminally substituted [2.2]paracyclophanes

The photoisomerization of the pseudo-geminal tetraene 11 furnishes the cyclooctadiene derivatives 13 and 15 with a completely new type of molecular bridge for a [2.2]paracyclophane which promise many interesting novel applications; the same is true for the photoisomerization of 22 to 23 and 24. The...

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Bibliographic Details
Main Authors: Henning Hopf, Vitaly Raev, Peter G. Jones
Format: Article
Language:English
Published: Beilstein-Institut 2011-05-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
paracyclophanes
photoadditions
photoisomerizations
proximity effects
topochemical reaction control
vinylcyclopropanes
X-ray structural analysis
Online Access:https://doi.org/10.3762/bjoc.7.78

Internet

https://doi.org/10.3762/bjoc.7.78

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