PH3 as a Phosphorus Source for Phosphinidene–Carbene Adducts and Phosphinidene–Transition Metal Complexes

The parent phosphinidene–carbene adduct NHC=PH is a versatile synthon in main group chemistry and can act as an electronically flexible ligand for transition metals. Previously, it could only be synthesized with sterically demanding N-aryl substituents. This paper describes simple methods...

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Bibliographic Details
Main Authors: Mark Bispinghoff, Hansjörg Grützmacher
Format: Article
Language:deu
Published: Swiss Chemical Society 2016-04-01
Series:CHIMIA
Subjects:
Online Access:https://www.chimia.ch/chimia/article/view/1753