Effects of Solvent and Monomer on the Kinetics of Radical Generation in Atom Transfer Radical Polymerization

Effects of Solvent and Monomer on the Kinetics of Radical Generation in Atom Transfer Radical Polymerization

Abstract Unlike classical radical polymerization, the kinetics of atom transfer radical polymerization show significant solvent dependence, possibly arising from solvent effects on the activation step. A kinetic study on the activation of the initiator ethyl α‐bromoisobutyrate by [CuITPMA]+ (TPMA=tr...

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Bibliographic Details
Main Authors: Dr. Marco Fantin, Enrico Tognella, Andrea Antonello, Dr. Francesca Lorandi, Elia Calore, Angelika Macior, Prof. Christian Durante, Prof. Abdirisak A. Isse
Format: Article
Language:English
Published: Wiley-VCH 2024-03-01
Series:ChemElectroChem
Subjects:
Activation kinetics
ATRP
medium effect
copper catalyst
LSER
Online Access:https://doi.org/10.1002/celc.202300662

Internet

https://doi.org/10.1002/celc.202300662

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