Copper-Catalyzed C(3+1) copolymerization of propargyl carbonates and aryldiazomethanes

Copper-Catalyzed C(3+1) copolymerization of propargyl carbonates and aryldiazomethanes

Controlling the composition and sequence during diazo copolymerization with vinyl or acetylenic monomers is highly desired yet challenging. Here we report a new base-metal-catalysis strategy to address this problem via tandem coupling/polymerization. A selective Cu-catalyzed C(3+1) copolymerization...

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Bibliographic Details
Main Authors: Hao-Ze Su, Bin Wu, Jianbo Wang, Rong Zhu
Format: Article
Language:English
Published: Elsevier 2023-03-01
Series:Giant
Subjects:
Copper
Diazo
Chain-growth polymerization
Hydrocarbon polymers
Alkynes
Online Access:http://www.sciencedirect.com/science/article/pii/S2666542523000012

Internet

http://www.sciencedirect.com/science/article/pii/S2666542523000012

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