DNA-Catalyzed Henry Reaction in Pure Water and the Striking Influence of Organic Buffer Systems

DNA-Catalyzed Henry Reaction in Pure Water and the Striking Influence of Organic Buffer Systems

In this manuscript we report a critical evaluation of the ability of natural DNA to mediate the nitroaldol (Henry) reaction at physiological temperature in pure water. Under these conditions, no background reaction took place (i.e., control experiment without DNA). Both heteroaromatic aldehydes (e.g...

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Bibliographic Details
Main Authors: Marleen Häring, Maria M. Pérez-Madrigal, Dennis Kühbeck, Asja Pettignano, Françoise Quignard, David Díaz Díaz
Format: Article
Language:English
Published: MDPI AG 2015-03-01
Series:Molecules
Subjects:
DNA
C–C bond formation
nitroaldol reaction
Henry reaction
buffer solutions
Online Access:http://www.mdpi.com/1420-3049/20/3/4136

Internet

http://www.mdpi.com/1420-3049/20/3/4136

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