Dielectric Properties Investigation of Metal–Insulator–Metal (MIM) Capacitors

This study presents the construction and dielectric properties investigation of atomic-layer-deposition Al<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub>/HfO<sub>2</sub> dielectric-film-based metal–insulator–metal (MIM) capacitors. The influence of the diele...

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Main Authors: Li Xiong, Jin Hu, Zhao Yang, Xianglin Li, Hang Zhang, Guanhua Zhang
Format: Article
Language:English
Published: MDPI AG 2022-06-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/27/12/3951
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author Li Xiong
Jin Hu
Zhao Yang
Xianglin Li
Hang Zhang
Guanhua Zhang
author_facet Li Xiong
Jin Hu
Zhao Yang
Xianglin Li
Hang Zhang
Guanhua Zhang
author_sort Li Xiong
collection DOAJ
description This study presents the construction and dielectric properties investigation of atomic-layer-deposition Al<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub>/HfO<sub>2</sub> dielectric-film-based metal–insulator–metal (MIM) capacitors. The influence of the dielectric layer material and thickness on the performance of MIM capacitors are also systematically investigated. The morphology and surface roughness of dielectric films for different materials and thicknesses are analyzed via atomic force microscopy (AFM). Among them, the 25 nm Al<sub>2</sub>O<sub>3</sub>-based dielectric capacitor exhibits superior comprehensive electrical performance, including a high capacitance density of 7.89 fF·µm<sup>−2</sup>, desirable breakdown voltage and leakage current of about 12 V and 1.4 × 10<sup>−10</sup> A·cm<sup>−2</sup>, and quadratic voltage coefficient of 303.6 ppm·V<sup>−2</sup>. Simultaneously, the fabricated capacitor indicates desirable stability in terms of frequency and bias voltage (at 1 MHz), with the corresponding slight capacitance density variation of about 0.52 fF·µm<sup>−2</sup> and 0.25 fF·µm<sup>−2</sup>. Furthermore, the mechanism of the variation in capacitance density and leakage current might be attributed to the Poole–Frenkel emission and charge-trapping effect of the high-<i>k</i> materials. All these results indicate potential applications in integrated passive devices.
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spelling doaj.art-3b6946a1386b4f9b97116de98d24275b2023-11-23T18:14:16ZengMDPI AGMolecules1420-30492022-06-012712395110.3390/molecules27123951Dielectric Properties Investigation of Metal–Insulator–Metal (MIM) CapacitorsLi Xiong0Jin Hu1Zhao Yang2Xianglin Li3Hang Zhang4Guanhua Zhang5State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, College of Mechanical and Vehicle Engineering, Hunan University, Changsha 410082, ChinaState Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, College of Mechanical and Vehicle Engineering, Hunan University, Changsha 410082, ChinaGuangdong Fenghua Advanced Technology Holding Co., Ltd., Zhaoqing 526060, ChinaSchool of Physics and Chemistry, Hunan First Normal University, Changsha 410205, ChinaKey Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an 710119, ChinaState Key Laboratory of Advanced Design and Manufacturing for Vehicle Body, College of Mechanical and Vehicle Engineering, Hunan University, Changsha 410082, ChinaThis study presents the construction and dielectric properties investigation of atomic-layer-deposition Al<sub>2</sub>O<sub>3</sub>/TiO<sub>2</sub>/HfO<sub>2</sub> dielectric-film-based metal–insulator–metal (MIM) capacitors. The influence of the dielectric layer material and thickness on the performance of MIM capacitors are also systematically investigated. The morphology and surface roughness of dielectric films for different materials and thicknesses are analyzed via atomic force microscopy (AFM). Among them, the 25 nm Al<sub>2</sub>O<sub>3</sub>-based dielectric capacitor exhibits superior comprehensive electrical performance, including a high capacitance density of 7.89 fF·µm<sup>−2</sup>, desirable breakdown voltage and leakage current of about 12 V and 1.4 × 10<sup>−10</sup> A·cm<sup>−2</sup>, and quadratic voltage coefficient of 303.6 ppm·V<sup>−2</sup>. Simultaneously, the fabricated capacitor indicates desirable stability in terms of frequency and bias voltage (at 1 MHz), with the corresponding slight capacitance density variation of about 0.52 fF·µm<sup>−2</sup> and 0.25 fF·µm<sup>−2</sup>. Furthermore, the mechanism of the variation in capacitance density and leakage current might be attributed to the Poole–Frenkel emission and charge-trapping effect of the high-<i>k</i> materials. All these results indicate potential applications in integrated passive devices.https://www.mdpi.com/1420-3049/27/12/3951energy storagemetal–insulator–metal capacitorsatomic layer depositionlaser direct writingelectrical performance
spellingShingle Li Xiong
Jin Hu
Zhao Yang
Xianglin Li
Hang Zhang
Guanhua Zhang
Dielectric Properties Investigation of Metal–Insulator–Metal (MIM) Capacitors
Molecules
energy storage
metal–insulator–metal capacitors
atomic layer deposition
laser direct writing
electrical performance
title Dielectric Properties Investigation of Metal–Insulator–Metal (MIM) Capacitors
title_full Dielectric Properties Investigation of Metal–Insulator–Metal (MIM) Capacitors
title_fullStr Dielectric Properties Investigation of Metal–Insulator–Metal (MIM) Capacitors
title_full_unstemmed Dielectric Properties Investigation of Metal–Insulator–Metal (MIM) Capacitors
title_short Dielectric Properties Investigation of Metal–Insulator–Metal (MIM) Capacitors
title_sort dielectric properties investigation of metal insulator metal mim capacitors
topic energy storage
metal–insulator–metal capacitors
atomic layer deposition
laser direct writing
electrical performance
url https://www.mdpi.com/1420-3049/27/12/3951
work_keys_str_mv AT lixiong dielectricpropertiesinvestigationofmetalinsulatormetalmimcapacitors
AT jinhu dielectricpropertiesinvestigationofmetalinsulatormetalmimcapacitors
AT zhaoyang dielectricpropertiesinvestigationofmetalinsulatormetalmimcapacitors
AT xianglinli dielectricpropertiesinvestigationofmetalinsulatormetalmimcapacitors
AT hangzhang dielectricpropertiesinvestigationofmetalinsulatormetalmimcapacitors
AT guanhuazhang dielectricpropertiesinvestigationofmetalinsulatormetalmimcapacitors