Reaction of a 3-aryilidene-2-thiohydantoin derivative with polymeric trans-[CuCl2(DMSO)2]n complex: Unexpected isomerization to dinuclear cis-[{CuCl(DMSO)2}(μ-Cl)]2

Reaction of a 3-aryilidene-2-thiohydantoin derivative with polymeric trans-[CuCl2(DMSO)2]n complex: Unexpected isomerization to dinuclear cis-[{CuCl(DMSO)2}(μ-Cl)]2

The 3-arylidene-2-thiohydantoin derivative, 3-[(2-hydroxybenzylidene) amino]-2-thioxoimidazolidin-4-one, was synthesized in a two-step condensation reaction of 2-hydroxybenzaldehyde, thiosemicarbazide and ethyl chloroacetate. The ligand was structurally characterized by NMR and IR spectroscopy, as w...

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Bibliographic Details
Main Authors: Stanić Petar B., Rodić Marko V., Soldatović Tanja V., Pavić Aleksandar B., Radaković Nataša S., Šmit Biljana M., Živković Marija D.
Format: Article
Language:English
Published: Serbian Chemical Society 2020-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
cu(ii) complex
spectroscopic characterization
single crystal x-ray analysis
antimicrobial activity
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2020/0352-51392000060S.pdf

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http://www.doiserbia.nb.rs/img/doi/0352-5139/2020/0352-51392000060S.pdf

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