Comprehensively Understanding the Transformation of Paramagnetic Tetramer to Spin-Paired Dimer in an S = ½ Molecular Crystal

In this study, we comparatively analyzed the variable-temperature crystal structures for two isomorphous salts, [1-benzyl-4-aminopyridinium][M(mnt)<sub>2</sub>] (M = Ni or Cu; mnt<sup>2−</sup> = maleonitriledithiolate; labeled as <b>APy-Ni</b> or <b>APy-Cu&l...

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Bibliographic Details
Main Authors: Yin Qian, Yan Gao, Lei Xu, Reinhard K. Kremer, Jin Zhang, Xiao-Ming Ren
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Magnetochemistry
Subjects:
Online Access:https://www.mdpi.com/2312-7481/11/2/8