The stereochemical course of 2-methylisoborneol biosynthesis

Both enantiomers of 2-methyllinalyl diphosphate (2-Me-LPP) were synthesized enantioselectively using Sharpless epoxidation as a key step and purification of enantiomerically enriched intermediates through HPLC separation on a chiral stationary phase. Their enzymatic conversion with 2-methylisoborneo...

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Bibliographic Details
Main Authors: Binbin Gu, Anwei Hou, Jeroen S. Dickschat
Format: Article
Language:English
Published: Beilstein-Institut 2022-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.18.82