Dioxygen Reactivity of Copper(I)/Manganese(II)-Porphyrin Assemblies: Mechanistic Studies and Cooperative Activation of O<sub>2</sub>

Dioxygen Reactivity of Copper(I)/Manganese(II)-Porphyrin Assemblies: Mechanistic Studies and Cooperative Activation of O<sub>2</sub>

The oxidation of transition metals such as manganese and copper by dioxygen (O<sub>2</sub>) is of great interest to chemists and biochemists for fundamental and practical reasons. In this report, the O<sub>2</sub> reactivities of 1:1 and 1:2 mixtures of [(TPP)Mn<sup>II&...

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Bibliographic Details
Main Authors: Runzi Li, Firoz Shah Tuglak Khan, Shabnam Hematian
Format: Article
Language:English
Published: MDPI AG 2022-02-01
Series:Molecules
Subjects:
manganese porphyrins
copper chelates
dioxygen chemistry
variable-temperature absorption spectroscopy
nuclear magnetic resonance spectroscopy
Online Access:https://www.mdpi.com/1420-3049/27/3/1000

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https://www.mdpi.com/1420-3049/27/3/1000

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