Effect of Ligand Substitution on Zero-Field Slow Magnetic Relaxation in Mononuclear Dy(III) β-Diketonate Complexes with Phenanthroline-Based Ligands

Effect of Ligand Substitution on Zero-Field Slow Magnetic Relaxation in Mononuclear Dy(III) β-Diketonate Complexes with Phenanthroline-Based Ligands

Herein, we report the synthesis, structure and magnetic properties of two mononuclear complexes of general formula [Dy(acac)<sub>3</sub>(L)], where L = 2,2-dimethyl-1,3-dioxolo[4,5-<i>f</i>][1,10] phenanthroline (<b>1</b>) or 1,10-phenanthroline-5,6-dione (<b&g...

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Bibliographic Details
Main Authors: Egor V. Gorshkov, Denis V. Korchagin, Elena A. Yureva, Gennadii V. Shilov, Mikhail V. Zhidkov, Alexei I. Dmitriev, Nikolay N. Efimov, Andrew V. Palii, Sergey M. Aldoshin
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Magnetochemistry
Subjects:
eight-coordinate dysprosium (III) complexes
acetylacetonate
single molecule magnets
ab initio calculations
Online Access:https://www.mdpi.com/2312-7481/8/11/151

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https://www.mdpi.com/2312-7481/8/11/151

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