Controllable photomechanical bending of metal-organic rotaxane crystals facilitated by regioselective confined-space photodimerization

The preparation of materials that display macro-mechanical responses to external stimuli is challenging. Here, the authors synthesize metal-organic rotaxane frameworks that contain photoactive axles as linkers; light irradiation triggers photodimerization of the ligands, which leads to macroscopic p...

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Bibliographic Details
Main Authors: Jun-shan Geng, Lei Mei, Yuan-yuan Liang, Li-yong Yuan, Ji-pan Yu, Kong-qiu Hu, Li-hua Yuan, Wen Feng, Zhi-fang Chai, Wei-qun Shi
Format: Article
Language:English
Published: Nature Portfolio 2022-04-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-022-29738-y