Cross-Metathesis of Methallyl Halides: Concise Enantioselective Formal Total Synthesis of (–)-Presphaerene

Cross-Metathesis of Methallyl Halides: Concise Enantioselective Formal Total Synthesis of (–)-Presphaerene

The cross-metathesis (CM) of methallyl halides catalyzed using four different ruthenium-based complexes—Grubbs catalyst, Grubbs second-generation catalyst, Hoveyda-Grubbs second-generation catalyst, and Stewart–Grubbs catalyst—was investigated. When methallyl chloride or bromide was reacted with a m...

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Bibliographic Details
Main Authors: Suresh Mandava, Jaun Koo, Jungjoong Hwang, Hari Krishna Nallapaneni, Haeil Park, Jongkook Lee
Format: Article
Language:English
Published: Frontiers Media S.A. 2020-06-01
Series:Frontiers in Chemistry
Subjects:
cross-metathesis
methallyl halide
Stewart–Grubbs catalyst
total synthesis
presphaerene
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2020.00494/full

Internet

https://www.frontiersin.org/article/10.3389/fchem.2020.00494/full

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