Synthesis, crystal structure and properties of the trigonal–bipyramidal complex tris(2-methylpyridine N-oxide-κO)bis(thiocyanato-κN)cobalt(II)

Synthesis, crystal structure and properties of the trigonal–bipyramidal complex tris(2-methylpyridine N-oxide-κO)bis(thiocyanato-κN)cobalt(II)

Reaction of Co(NCS)2 with 2-methylpyridine N-oxide in a 1:3 ratio in n-butanol leads to the formation of crystals of tris(2-methylpyridine N-oxide-κO)bis(thiocyanato-κN)cobalt(II), [Co(NCS)2(C6H7NO)3]. The asymmetric unit of the title compound consists of one CoII cation two thiocyanate anions and t...

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Bibliographic Details
Main Authors: Christian Näther, Inke Jess
Format: Article
Language:English
Published: International Union of Crystallography 2024-05-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
synthesis
crystal structure
discrete complex
trigonal–bipyramidal coordination
thermal properties
cobalt thiocyanate
2-methylpyridine n-oxide
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989024003050

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http://scripts.iucr.org/cgi-bin/paper?S2056989024003050

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