Finite Heterogeneous Rate Constants for the Electrochemical Oxidation of VO2+ at Glassy Carbon Electrodes

The electrochemical oxidation of VO2+ at planar glassy carbon electrodes is investigated via stationary and rotating linear sweep voltammetry as well as via chronoamperometry. It is demonstrated that introducing finite kinetic rate constants into the Butler-Volmer equation captures the experimentall...

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Bibliographic Details
Main Authors: Tim Tichter, Jonathan Schneider, Christina Roth
Format: Article
Language:English
Published: Frontiers Media S.A. 2020-10-01
Series:Frontiers in Energy Research
Subjects:
Online Access:https://www.frontiersin.org/article/10.3389/fenrg.2020.00155/full