Heterobimetallic One-Dimensional Coordination Polymers MICuII (M = Li and K) Based on Ferromagnetically Coupled Di- and Tetracopper(II) Metallacyclophanes

Heterobimetallic One-Dimensional Coordination Polymers MICuII (M = Li and K) Based on Ferromagnetically Coupled Di- and Tetracopper(II) Metallacyclophanes

The synthesis, crystal structure and magnetic properties of the coordination polymers of formula [EDAP{Li6(H2O)8[(Cu2(μ-mpba)2)2(H2O)2]}]n (1) and [(EDAP)2{K(H2O)4[Cu2(μ-mpba)2(H2O)2]}Cl·2H2O]n (2), in which mpba = N,N′-1,3-phenylenebis(oxamate) and EDAP2+ = 1,1&am...

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Bibliographic Details
Main Authors: Tamyris T. da Cunha, Willian X. C. Oliveira, Emerson F. Pedroso, Francesc Lloret, Miguel Julve, Cynthia L. M. Pereira
Format: Article
Language:English
Published: MDPI AG 2018-08-01
Series:Magnetochemistry
Subjects:
oxamate
copper(II)
crystal engineering
spin polarization
ferromagnetic coupling
coordination polymers
Online Access:http://www.mdpi.com/2312-7481/4/3/38

Internet

http://www.mdpi.com/2312-7481/4/3/38

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