Near-IR Electrochromic Film with High Optical Contrast and Stability Prepared by Oxidative Electropolymerization of Triphenylamine Modified Terpyridine Platinum(II) Chloride

Near-IR Electrochromic Film with High Optical Contrast and Stability Prepared by Oxidative Electropolymerization of Triphenylamine Modified Terpyridine Platinum(II) Chloride

Terpyridine (TPY) platinum(II) chloride with a triphenylamine (TPA) group was successfully synthesized. The strong intramolecular Donor(TPA)-Acceptor(TPY) interaction induced the low-energy absorption band, mixing the spin-allowed singlet dπ(Pt)→π*(TPY) metal-to-ligand charge transfer (MLCT) with th...

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Bibliographic Details
Main Authors: Huiying Gu, Xiaomeng Sun, Qian Zhao, Hongwei Wang, Xinfeng Cheng, Chunxia Yang, Dongfang Qiu
Format: Article
Language:English
Published: MDPI AG 2023-12-01
Series:Molecules
Subjects:
terpyridine platinum(II) chloride
triphenylamine
electropolymerization
metallopolymer
near-IR electrochromism
Online Access:https://www.mdpi.com/1420-3049/28/24/8027

Internet

https://www.mdpi.com/1420-3049/28/24/8027

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