{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) toluene monosolvate

The reaction of (η3-allyl)[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) with tris(2,4-di-tert-butylphenyl)phosphite in toluene produces the title compound, [Rh(C42H62O3P)(C8H12)]·C7H8, by spontaneous metallation at one of the nonsubstituted phenyl ortho-C atoms o...

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Bibliographic Details
Main Authors: Detlef Selent, Anke Spannenberg, Armin Börner
Format: Article
Language:English
Published: International Union of Crystallography 2012-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812002851