{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) toluene monosolvate
The reaction of (η3-allyl)[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) with tris(2,4-di-tert-butylphenyl)phosphite in toluene produces the title compound, [Rh(C42H62O3P)(C8H12)]·C7H8, by spontaneous metallation at one of the nonsubstituted phenyl ortho-C atoms o...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812002851 |
| _version_ | 1831692213660155904 |
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| author | Detlef Selent Anke Spannenberg Armin Börner |
| author_facet | Detlef Selent Anke Spannenberg Armin Börner |
| author_sort | Detlef Selent |
| collection | DOAJ |
| description | The reaction of (η3-allyl)[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) with tris(2,4-di-tert-butylphenyl)phosphite in toluene produces the title compound, [Rh(C42H62O3P)(C8H12)]·C7H8, by spontaneous metallation at one of the nonsubstituted phenyl ortho-C atoms of the phosphite molecule. The coordination geometry at the RhI ion is distorted square-planar. The toluene solvent molecule is disordered over two different orientations, with site-occupation factors of 0.810 (2) and 0.190 (2). |
| first_indexed | 2024-12-20T11:49:40Z |
| format | Article |
| id | doaj.art-44bb7a4d86644db08e4b977202ad1a7a |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:49:40Z |
| publishDate | 2012-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-44bb7a4d86644db08e4b977202ad1a7a2022-12-21T19:41:49ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682m215m21510.1107/S1600536812002851{2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) toluene monosolvateDetlef SelentAnke SpannenbergArmin BörnerThe reaction of (η3-allyl)[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) with tris(2,4-di-tert-butylphenyl)phosphite in toluene produces the title compound, [Rh(C42H62O3P)(C8H12)]·C7H8, by spontaneous metallation at one of the nonsubstituted phenyl ortho-C atoms of the phosphite molecule. The coordination geometry at the RhI ion is distorted square-planar. The toluene solvent molecule is disordered over two different orientations, with site-occupation factors of 0.810 (2) and 0.190 (2).http://scripts.iucr.org/cgi-bin/paper?S1600536812002851 |
| spellingShingle | Detlef Selent Anke Spannenberg Armin Börner {2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) toluene monosolvate Acta Crystallographica Section E |
| title | {2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) toluene monosolvate |
| title_full | {2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) toluene monosolvate |
| title_fullStr | {2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) toluene monosolvate |
| title_full_unstemmed | {2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) toluene monosolvate |
| title_short | {2-[Bis(2,4-di-tert-butylphenoxy)phosphanyloxy-κP]-3,5-di-tert-butylphenyl-κC1}[(1,2,5,6-η)-cycloocta-1,5-diene]rhodium(I) toluene monosolvate |
| title_sort | 2 bis 2 4 di tert butylphenoxy phosphanyloxy amp 954 p 3 5 di tert butylphenyl amp 954 c1 1 2 5 6 amp 951 cycloocta 1 5 diene rhodium i toluene monosolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812002851 |
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