Deposition of diamond films by microwave plasma CVD on 4H-SiC substrates

Diamond films were deposited on 4H-SiC substrates by microwave plasma chemical vapor deposition (MPCVD). The substrate pretreatment method of electrostatic adsorption of seed crystals by nanodiamond suspensions was used, and the nucleation density of diamond on the substrate surface reached 10 ^10 /...

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Main Authors: Shasha Wei, Renqi Xie, Yuanyou Li, Jiahao Meng, Rongchuan Lin, Jianchun Weng, Bo Li
Format: Article
Language:English
Published: IOP Publishing 2023-01-01
Series:Materials Research Express
Subjects:
Online Access:https://doi.org/10.1088/2053-1591/ad094f
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author Shasha Wei
Renqi Xie
Yuanyou Li
Jiahao Meng
Rongchuan Lin
Jianchun Weng
Bo Li
author_facet Shasha Wei
Renqi Xie
Yuanyou Li
Jiahao Meng
Rongchuan Lin
Jianchun Weng
Bo Li
author_sort Shasha Wei
collection DOAJ
description Diamond films were deposited on 4H-SiC substrates by microwave plasma chemical vapor deposition (MPCVD). The substrate pretreatment method of electrostatic adsorption of seed crystals by nanodiamond suspensions was used, and the nucleation density of diamond on the substrate surface reached 10 ^10 /cm ^2 compared with ultrasonic seed crystals of diamond micro-powder suspensions, and continuous dense diamond films were formed in a shorter growth time. Scanning electron microscopy and Raman spectroscopy were used to characterize the changes of diamond grain morphology and quality with methane concentration, deposition time and substrate temperature during the growth process. The experimental results show that the methane concentration, deposition time and substrate temperature are the key factors affecting the grain shape and quality of diamond. And the best quality of diamond film is obtained at 850 °C substrate temperature.
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spelling doaj.art-4505097758234c139fb6f26afcd24d112023-12-27T15:35:04ZengIOP PublishingMaterials Research Express2053-15912023-01-01101212640410.1088/2053-1591/ad094fDeposition of diamond films by microwave plasma CVD on 4H-SiC substratesShasha Wei0Renqi Xie1https://orcid.org/0009-0004-7348-5624Yuanyou Li2https://orcid.org/0009-0006-4092-2511Jiahao Meng3Rongchuan Lin4Jianchun Weng5Bo Li6School of Science, Jimei University , Xiamen, 361021, People’s Republic of ChinaSchool of Science, Jimei University , Xiamen, 361021, People’s Republic of ChinaSchool of Science, Jimei University , Xiamen, 361021, People’s Republic of ChinaSchool of Science, Jimei University , Xiamen, 361021, People’s Republic of ChinaSchool of Science, Jimei University , Xiamen, 361021, People’s Republic of ChinaSchool of Science, Jimei University , Xiamen, 361021, People’s Republic of ChinaSchool of Science, Jimei University , Xiamen, 361021, People’s Republic of ChinaDiamond films were deposited on 4H-SiC substrates by microwave plasma chemical vapor deposition (MPCVD). The substrate pretreatment method of electrostatic adsorption of seed crystals by nanodiamond suspensions was used, and the nucleation density of diamond on the substrate surface reached 10 ^10 /cm ^2 compared with ultrasonic seed crystals of diamond micro-powder suspensions, and continuous dense diamond films were formed in a shorter growth time. Scanning electron microscopy and Raman spectroscopy were used to characterize the changes of diamond grain morphology and quality with methane concentration, deposition time and substrate temperature during the growth process. The experimental results show that the methane concentration, deposition time and substrate temperature are the key factors affecting the grain shape and quality of diamond. And the best quality of diamond film is obtained at 850 °C substrate temperature.https://doi.org/10.1088/2053-1591/ad094fmicrowave plasma CVD4H-SiCsubstrate pretreatmentdiamond films
spellingShingle Shasha Wei
Renqi Xie
Yuanyou Li
Jiahao Meng
Rongchuan Lin
Jianchun Weng
Bo Li
Deposition of diamond films by microwave plasma CVD on 4H-SiC substrates
Materials Research Express
microwave plasma CVD
4H-SiC
substrate pretreatment
diamond films
title Deposition of diamond films by microwave plasma CVD on 4H-SiC substrates
title_full Deposition of diamond films by microwave plasma CVD on 4H-SiC substrates
title_fullStr Deposition of diamond films by microwave plasma CVD on 4H-SiC substrates
title_full_unstemmed Deposition of diamond films by microwave plasma CVD on 4H-SiC substrates
title_short Deposition of diamond films by microwave plasma CVD on 4H-SiC substrates
title_sort deposition of diamond films by microwave plasma cvd on 4h sic substrates
topic microwave plasma CVD
4H-SiC
substrate pretreatment
diamond films
url https://doi.org/10.1088/2053-1591/ad094f
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AT jiahaomeng depositionofdiamondfilmsbymicrowaveplasmacvdon4hsicsubstrates
AT rongchuanlin depositionofdiamondfilmsbymicrowaveplasmacvdon4hsicsubstrates
AT jianchunweng depositionofdiamondfilmsbymicrowaveplasmacvdon4hsicsubstrates
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