Nickel-aluminium pincer complexes undergo cooperative bond activation

Lewis acid additives such as aluminium can enable fascinating new reactivity in transition metal catalysts, but few catalytic intermediates have been characterised. Now, a nickel-aluminium pincer complex offers new mechanistic insight into transmetalation, and new potential for reactivity.

Bibliographic Details
Main Author: Andrew J. Bissette
Format: Article
Language:English
Published: Nature Portfolio 2021-05-01
Series:Communications Chemistry
Online Access:https://doi.org/10.1038/s42004-021-00519-w