Versatile Reactivity of Mn<sup>II</sup> Complexes in Reactions with N-Donor Heterocycles: Metamorphosis of Labile Homometallic Pivalates vs. Assembling of Endurable Heterometallic Acetates

Versatile Reactivity of Mn<sup>II</sup> Complexes in Reactions with N-Donor Heterocycles: Metamorphosis of Labile Homometallic Pivalates vs. Assembling of Endurable Heterometallic Acetates

Reaction of 2,2′-bipyridine (2,2′-bipy) or 1,10-phenantroline (phen) with [Mn(Piv)<sub>2</sub>(EtOH)]<i><sub>n</sub></i> led to the formation of binuclear complexes [Mn<sub>2</sub>(Piv)<sub>4</sub>L<sub>2</sub>] (L = 2,2′-bipy (...

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Bibliographic Details
Main Authors: Ruslan A. Polunin, Igor S. Evstifeev, Olivier Cador, Stéphane Golhen, Konstantin S. Gavrilenko, Anton S. Lytvynenko, Nikolay N. Efimov, Vadim V. Minin, Artem S. Bogomyakov, Lahcène Ouahab, Sergey V. Kolotilov, Mikhail A. Kiskin, Igor L. Eremenko
Format: Article
Language:English
Published: MDPI AG 2021-02-01
Series:Molecules
Subjects:
polynuclear complexes
manganese
pyridines
coordination polymers
porous materials
magnetic properties
Online Access:https://www.mdpi.com/1420-3049/26/4/1021

Internet

https://www.mdpi.com/1420-3049/26/4/1021

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