<em>In Situ</em> Electrochemical SFG/DFG Study of CN<sup>−</sup> and Nitrile Adsorption at Au from 1-Butyl-1-methyl-pyrrolidinium Bis(trifluoromethylsulfonyl) Amide Ionic Liquid ([BMP][TFSA]) Containing 4-{2-[1-(2-Cyanoethyl)-1,2,3,4-tetrahydroquinolin-6-yl]diazenyl} Benzonitrile (CTDB) and K[Au(CN)<sub>2</sub>]

<em>In Situ</em> Electrochemical SFG/DFG Study of CN<sup>−</sup> and Nitrile Adsorption at Au from 1-Butyl-1-methyl-pyrrolidinium Bis(trifluoromethylsulfonyl) Amide Ionic Liquid ([BMP][TFSA]) Containing 4-{2-[1-(2-Cyanoethyl)-1,2,3,4-tetrahydroquinolin-6-yl]diazenyl} Benzonitrile (CTDB) and K[Au(CN)<sub>2</sub>]

In this paper we report an<em> in situ</em> electrochemical Sum-/Difference Frequency Generation (SFG/DFG) spectroscopy investigation of the adsorption of nitrile and CN<sup>−</sup> from the ionic liquid 1-butyl-1-methyl-pyrrolidinium bis(trifl...

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Bibliographic Details
Main Authors: Benedetto Bozzini, Bertrand Busson, Audrey Gayral, Christophe Humbert, Claudio Mele, Catherine Six, Abderrahmane Tadjeddine
Format: Article
Language:English
Published: MDPI AG 2012-06-01
Series:Molecules
Subjects:
1-butyl-1-methyl-pyrrolidinium bis(trifluoromethylsulfonyl) amide
4-{2-[1-(2-cyanoethyl)-1,2,3,4-tetrahydroquinolin-6-yl]diazenyl} benzonitrile
Au
electrodeposition
non-linear spectroscopy
spectroelectrochemistry
SFG
DFG
Online Access:http://www.mdpi.com/1420-3049/17/7/7722

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http://www.mdpi.com/1420-3049/17/7/7722

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