Size selective recognition of small esters by a negative allosteric hemicarcerand
A bis(resorcinarene) substituted 2,2′-bipyridine was found to bind weakly to small esters like ethyl acetate whereas more bulky esters were not recognized by this hemicarcerand. This size selective molecular recognition could be controlled by a negative cooperative allosteric effect: coordination of...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
Beilstein-Institut
2010-02-01
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Series: | Beilstein Journal of Organic Chemistry |
Subjects: | |
Online Access: | https://doi.org/10.3762/bjoc.6.10 |