Size selective recognition of small esters by a negative allosteric hemicarcerand

A bis(resorcinarene) substituted 2,2′-bipyridine was found to bind weakly to small esters like ethyl acetate whereas more bulky esters were not recognized by this hemicarcerand. This size selective molecular recognition could be controlled by a negative cooperative allosteric effect: coordination of...

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Bibliographic Details
Main Authors: Holger Staats, Arne Lützen
Format: Article
Language:English
Published: Beilstein-Institut 2010-02-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.6.10