A Triplet/Singlet Ground-State Switch via the Steric Inhibition of Conjugation in 4,6-Bis(trifluoromethyl)-1,3-phenylene Bisnitroxide
Ground triplet 4,6-bis(trifluoromethyl)-1,3-phenylene bis(<i>tert</i>-butyl nitroxide) (TF2PBN) reacted with [Y(hfac)<sub>3</sub>(H<sub>2</sub>O)<sub>2</sub>] (hfac = 1,1,1,5,5,5-hexafluoropentane-2,4-dionate), affording a doubly hydrogen-bonded adduct...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2023-12-01
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| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/29/1/70 |