Rapid atom-efficient polyolefin plastics hydrogenolysis mediated by a well-defined single-site electrophilic/cationic organo-zirconium catalyst

Polyolefins are a major fraction of plastic waste, yet their catalytic recycling is challenging due to their inert hydrocarbon structures. Here a well-defined supported organozirconium catalyst is shown to mediate the rapid hydrogenolytic cleavage diverse polyolefins under very mild conditions.

Bibliographic Details
Main Authors: Alexander H. Mason, Alessandro Motta, Anusheela Das, Qing Ma, Michael J. Bedzyk, Yosi Kratish, Tobin J. Marks
Format: Article
Language:English
Published: Nature Portfolio 2022-11-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-022-34707-6