Ultrafast electronic and vibrational dynamics in brominated aluminum corroles: Energy relaxation and triplet formation
We combined femtosecond (fs) VIS pump–IR probe spectroscopy with fs VIS pump–supercontinuum probe spectroscopy to characterize the photoreaction of the hexacoordinated Al(tpfc-Br8)(py)2 in a comprehensive way. Upon fs excitation at ∼400 nm in the Soret band, the excitation energy relaxes with a time...
Main Authors: | , , , , , |
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Format: | Article |
Language: | English |
Published: |
AIP Publishing LLC and ACA
2016-07-01
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Series: | Structural Dynamics |
Online Access: | http://dx.doi.org/10.1063/1.4949363 |