Ultrafast electronic and vibrational dynamics in brominated aluminum corroles: Energy relaxation and triplet formation

We combined femtosecond (fs) VIS pump–IR probe spectroscopy with fs VIS pump–supercontinuum probe spectroscopy to characterize the photoreaction of the hexacoordinated Al(tpfc-Br8)(py)2 in a comprehensive way. Upon fs excitation at ∼400 nm in the Soret band, the excitation energy relaxes with a time...

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Bibliographic Details
Main Authors: T. Stensitzki, Y. Yang, A. Berg, A. Mahammed, Z. Gross, K. Heyne
Format: Article
Language:English
Published: AIP Publishing LLC and ACA 2016-07-01
Series:Structural Dynamics
Online Access:http://dx.doi.org/10.1063/1.4949363