Syntheses and crystal structure of a (2,6-diisopropyldinaphtho[2,1-d:1′,2′-f][1,3]dithiepin-4-yl)(phenyl)methanol atropisomer

Syntheses and crystal structure of a (2,6-diisopropyldinaphtho[2,1-d:1′,2′-f][1,3]dithiepin-4-yl)(phenyl)methanol atropisomer

The racemic title compound, C34H32OS2, comprises an atropisomeric binaphthyl dithioacetal substituted at the methylene carbon atom with a chiral benzyl alcohol. The two naphthalene ring systems are additionally substituted at the 3,3′-position with isopropyl groups. The overall stereochemistry is de...

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Bibliographic Details
Main Authors: Neil Beare, Gavin F. Painter, C. John McAdam
Format: Article
Language:English
Published: International Union of Crystallography 2023-03-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
atropisomer
binaphthalene dithiol
asymmetric synthesis
hydrogen bonds
c—h...π contacts
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989023001706

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http://scripts.iucr.org/cgi-bin/paper?S2056989023001706

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