Synthesis of dipolar molecular rotors as linkers for metal-organic frameworks

Synthesis of dipolar molecular rotors as linkers for metal-organic frameworks

We report the synthesis of five dicarboxylic acid-substituted dipolar molecular rotors for the use as linker molecules in metal-organic frameworks (MOFs). The rotor molecules exhibit very low rotational barriers and decent to very high permanent, charge free dipole moments, as shown by density funct...

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Bibliographic Details
Main Authors: Sebastian Hamer, Fynn Röhricht, Marius Jakoby, Ian A. Howard, Xianghui Zhang, Christian Näther, Rainer Herges
Format: Article
Language:English
Published: Beilstein-Institut 2019-06-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
benzothiadiazole
dipolar rotor
fluorescence
large dipole moment
metal organic framework linker
Online Access:https://doi.org/10.3762/bjoc.15.132

Internet

https://doi.org/10.3762/bjoc.15.132

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